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Novel, efficient, and recyclable bifunctional catalysts bearing SiO 2 -supported RuCl 3 and iodoarene moieties were developed and used for environmentally benign oxidation of alcohols or alkylarenes at the benzylic position. These reactions in the presence of oxone as stoichiometric oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient...
At oxidizing of liquid zinc by H2O/CO2 mixture at supercritical parameters it is found the formation of nanoparticles (ZnO)n with size from 1.5 to 100 nm and combustible substances: H2, CO, lower paraffin and aromatic hydrocarbons, alcohols and formaldehyde. Composition of combustible products depends on H2O/CO2 ratio in mixture. Synthesized ZnO samples were studied by methods of scanning and transmission...
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