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Hydrogen peroxide oxidation of cyclohexane in acetonitrile solution catalyzed by the dinuclear manganese(IV) complex [LMn(O) 3 MnL](PF 6 ) 2 (L=1,4,7-trimethyl-1,4,7-triazacyclononane, TMTACN) at 25°C in the presence of a carboxylic acid affords cyclohexyl hydroperoxide as well as cyclohexanone and cyclohexanol. A kinetic study of the reactions with participation of three acids...
The manganese(IV) complex salt [L2Mn2O3](PF6)2 (L=1,4,7-trimethyl-1,4,7-triazacyclononane) (compound 1, see Scheme 1Scheme 1Manganese derivatives used in this work as catalysts of oxidation reactions.) very efficiently catalyzes the hydroperoxidation of saturated hydrocarbons, including ethane by H2O2 in acetontitrile or nitromethane solution at low (room or lower) temperature, provided a carboxylic...
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