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The adsorption, from aqueous solution, of (S)-aspartic acid onto polycrystalline Ni was investigated as a function of pH via X-ray photoelectron spectroscopy in order to investigate why the hydrogenation of β-ketoesters over aspartic acid-modified Ni catalysts exhibits a very sharp maximum in enantioselectivity at modification pH 5. Following similar modification and washing procedures to those used...
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