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This review examines the synthesis, properties, and acid reactivity of transition metal dinitrogen complexes bearing phosphine ligands containing pendant amine groups in the second coordination sphere. We have synthesized non-precious metal dinitrogen complexes containing bidentate, tridentate, and tetradentate phosphine ligands, some of which generate N2 derived ammonia and/or hydrazine in the presence...
Four different transition catalysts (V, Cr, Zn, Mo) supported on TiO2 were prepared by incipient impregnation and their performances of selective catalytic oxidation (SCO) of ammonia(NH3) were investigated in mixed gas in which 500ppm ammonia was included and the gas hourly space velocity(GHSV) was 35385h-1. The results shown that 99% ammonia removal efficiency, 19% nitric oxide (NO) conversion and...
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