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Ionic liquids (ILs) can behave as green solvents in comparison with conventional organic solvents, but more often they also act as ligands, co‐catalysts, and stabilizing agents both for metal active species and for intermediates of catalytic systems. In this review we have mainly summarized the recent achievements (2013 to the present) in Pd‐catalyzed cross‐coupling in ILs for the assembly of structurally...
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