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The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators during the last decades, the actual understanding of the thermal decomposition kinetics is still very limited. Thus, while several mechanisms have been proposed to describe the process, the real model has not yet been clearly identified. In this paper, a set of experimental curves...
This paper explores the relationship between the shapes of temperature–time curves obtained from experimental data recorded by means of constant rate thermal analysis (CRTA) and the kinetic model followed by the thermal degradation reaction. A detailed shape analysis of CRTA curves has been performed as a function of the most common kinetic models. The analysis has been validated with simulated data,...
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