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Six Ru(II) complexes with formula [Ru(terpy)(L)]X (L=tridentate N,N,S− donor thiosemicarbazone ligands, X=PF6−) have been synthesized and characterized by using standard analytical and spectroscopic techniques. The X-ray crystal structures of the complexes [Ru(terpy)(L2)]PF6(2) and [Ru(terpy)(L3)]PF6(3) have been determined. It was found that during complexation the hydroxyimino functionality of the...
This paper presents a combined experimental and computational study of Ru(II) carbonyl complexes containing thiosemicarbazone ligands. Five novel [Ru(H/Cl)(L)(PPh 3 ) 2 ] complexes have been obtained and characterized by IR, 1 H, 13 C, 31 P NMR, UV–Vis spectroscopy and X-ray crystallography. Their electronic structures have been determined using the density...
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