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The concept of “slow release anions for the assembly of crystals” was successfully carried out through a facile, effective and environmental friendly supersonic and microwave co-assistance (SMC) approach at very low temperature in less than 40min. It has been found that the rational design of multiple irradiations, lanthanide contraction and fluoride sources would make it possible to control both...
A facile sonochemical and the microwave co-assisted method (SMC) with low temperature (70°C) has been applied to synthesize a series of rare earth orthovanadates LnVO 4 with the tetragonal zircon structures. XRD patterns indicate that the average crystallite sizes gradually increase with the decrease of the ions radii of the rare earth, SEM images show that different lanthanide ions triggered...
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