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The direct synthesis of methanethiol, CH 3 SH, from CO and H 2 S was investigated using sulfided vanadium catalysts based on TiO 2 and Al 2 O 3 . These catalysts yield high activity and selectivity to methanethiol at an optimized temperature of 615K. Carbonyl sulfide and hydrogen are predominant products below 615K, whereas above this temperature methane becomes...
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