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Methanol adsorption on stoichiometric and defective TiO 2 (110) surfaces was studied by means of TPRS and XPS. Anion vacancy defects were created by electron bombardment in order to minimize the structural damage inflicted to the surface. Methanol adsorbed dissociatively on the TiO 2 (110) surfaces at room temperature, forming methoxide and hydroxide groups. On the stoichiometric surface...
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