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Palladium overlayers deposited on TiO 2 (110) by metal vapour deposition have been investigated using LEED, XPS and FT-RAIRS of adsorbed CO. Low coverages of palladium (< 3 ML) deposited at 300 K adsorb CO exclusively in a bridged configuration with a band (B 1 at 1990 cm -1 ) characteristic of CO adsorption on Pd(110) and Pd(100) surfaces. When annealed to 500 K, XPS...
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