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The thermal decomposition of lutetium nitrate starts with essentially a process of dehydration of the initial monomer Lu(NO3)3·3H2O with further condensation into a hexamer Lu6N18O54·6H2O. The latter decomposes in four steps with release of water, azeotrope 68% HNO3–32% H2O, nitric acid, nitrogen dioxide and oxygen. The resulting intermediate compounds are lutetium oxynitrates Lu6N4O19 and Lu6N2O14...
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