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The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate how polyoxometalate (POM)‐based heterogeneous compounds functionalized with Platinum particles activate H2 by synergism between a hydrogen spillover mechanism and electron‐proton transfer by the POM. This interplay facilitates the selective catalytic reduction of olefins and nitroarenes with high functional group...
The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate how polyoxometalate (POM)‐based heterogeneous compounds functionalized with Platinum particles activate H2 by synergism between a hydrogen spillover mechanism and electron‐proton transfer by the POM. This interplay facilitates the selective catalytic reduction of olefins and nitroarenes with high functional group...
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