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Through a combination of standard laboratory-based surface science methods, together with synchrotron radiation-based normal incidence X-ray standing wave (NIXSW) experiments, the interface structure of simple alkylthiolate ‘self-assembled monolayers’ on Cu(111), Ag(111) and Au(111) has been investigated over the last ∼15 years. A key conclusion is that in all cases the adsorbate produces a substantial,...
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