The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
From traditional to sustainable: Catalysts with platinum‐group metals are well‐established in the field of hydroboration of C−C multiple bonds. However, the current mantra in catalysis is to employ “cheap metals for noble tasks”. In this regard, we have developed a bis(phosphino)carbazolido magnesium‐methyl complex as a catalyst for the hydroboration of alkenes, alkynes, and biologically essential...
In this work, two monomeric magnesium alkyl complexes (1 and 2) were prepared using bis(phosphino)carbazole framework and among them 1 has been used as a catalyst for hydroboration of alkenes and alkynes with pinacolborane (HBpin). A broad variety of aromatic and aliphatic alkenes and alkynes were efficiently reduced. Anti‐Markovnikov regioselective hydroboration of alkenes and alkynes was achieved,...