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Supramolecular coordination‐driven self‐assembly rectangle 1a have be formation of distorted shapes, with a strong π···π interactions between the L1 and anthracene in 1b (1a ⊃ anthracene) that changed the size to desired and supported by single‐crystal Xray diffraction data. The formation of 1c(1a ⊃ DMF) has been further corroborated by the single‐crystal and 1b also can reaction with decaborane to...
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