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A series of blue‐emitting phosphorescent mono‐cyclometalated AuIII complexes have been successfully synthesized. Tailoring the substitutions on the phenylpyridine (ppy) ligand scaffold with electron‐withdrawing fluorine groups on the phenyl ring to achieve stabilization of the HOMO and an electron‐donating dimethylamino group on the pyridine ring to destabilize the LUMO resulted in a large energy...
Blue emitting phosphorescent monocyclometalated AuIII complexes were obtained by tailoring substitutions at the phenylpyridine ligand scaffold with electron‐withdrawing groups at the phenyl ring to achieve stabilization of the HOMO and an electron‐donating group on the pyridine ring to destabilize the LUMO, resulting in a large energy gap. This bestowed the gold complexes with emission at high energies...
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