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Silver carboxylate coordination with the tetrachlorophthalate anion, in combination with neutral donor ligands, has been found to deviate from other known poly-carboxylate complexes. Both complexes reported here, bis-[tetrachlorophthalato-silver phthalazine] and bis-[ammino-tetrachlorophthato-silver di-ammino-silver], utilize mixed carboxylate bonding types for silver coordination. In the case of...
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