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Catalytic carbonylations of aryl electrophiles via C(sp2)−N cleavage remains a significant challenge. Herein, we demonstrate an aminocarbonylation of aniline‐derived trialkylammonium salts promoted by visible light with a simple cobalt catalyst. The reaction proceeds under mild conditions suitable for late‐stage functionalization and is amenable to telescoped carbonylations directly from anilines...
Catalytic carbonylations of aryl electrophiles via C(sp2)−N cleavage remains a significant challenge. Herein, we demonstrate an aminocarbonylation of aniline‐derived trialkylammonium salts promoted by visible light with a simple cobalt catalyst. The reaction proceeds under mild conditions suitable for late‐stage functionalization and is amenable to telescoped carbonylations directly from anilines...
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