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Thermoelectric properties of ternary silver thallium tellurides: Ag8T12Te5 and AgT13Te2 were studied above room temperature to slightly below the melting temperature. As for Ag8T12Te5, the effects of Te content on the thermoelectric properties were also studied by characterizing the samples of Ag8T12Tex (x = 5.0, 5.1, 5.2). Both compounds show positive Seebeck coefficient (S). Ag8T12Te5 indicates...
Bulk nanostructured (Bi,Sb)2Te3 compounds and GeTe based amorphous/nanocrystal composites have been successfully fabricated by the combined hydrothermal/hot-pressing and quenching/annealing methods, respectively. The (Bi,Sb)2Te3 nanopowders synthesized by hydrothermal method exhibit a hollow-like structure. After hot-pressing, the nanoscale grains varying from tens to hundreds of nanometers were found...
The SrTiO3 and Y-doped SrTiO3 polycrystalline sintered bodies were synthesized by the polymerized complex (PC) process and the subsequent hot pressing at 1473 K for 1 h or at 1673 K for 2 h in Ar atmosphere. The X-ray diffraction patterns of the SrTiO3 and Sr0.9Y0.1TiO3 samples synthesized by the PC process and hot pressing at 1473 K showed that these samples were mostly composed of the SrTiO3 single...
To study the effect of double filling of the skutterudite iron antimonides on the thermal conductivity, we have synthesized dense samples of Ca1-xLaxFe4Sb12 (0 les times les 1) and Ca0.3La0.6Fe4-yCoySb12 (y = 1, 1.5) by the spark plasma sintering technique. Electron-probe microanalysis revealed that the double-filled samples with x = 0.25, 0.5, and 0.75 consist of three phases of micrometer scale;...
Hf1-xZrxTe5, which is expected to have high thermoelectric performance at low temperature, is investigated on polycrystals with high density. in order to examine the possibility of large enhancement of the figure of merit at low temperature, polycrystalline samples of Hf1-xZrxTe5 (x=0.0, 0.5 and 1.0) are systhesized by hot-press sintering to make high density above ~90%. Resultant polycrystals show...
In this study, we fabricated in-plane thermoelectric micro-generators (4 mm times 4 mm) based on bismuth telluride thin films by using flash evaporation method. The thermoelectric properties of as-grown thin films are lower than those of bulk materials. Therefore the as-grown thin films were annealed in hydrogen at atmospheric pressure for 1 hour in a temperature range of 200 degC. to 400degC. By...
The effects of Ce doping and reduction on the superconductivity and electronic state of Nd2-xCexCuO4-∂ were investigated through measurements of the magnetization and X-ray absorption near-edge structure of the Cu-K edge of specimens annealed at various oxygen pressures and temperatures. The superconduction onset temperature and diamagnetism reach a peak at a Ce content of x=0.15. We found that the...
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