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The X-ray photoelectron spectra for Re_{3}Fe_{5}O_{12} garnets, ReFeO_{3} orthoferrites and ReVO_{4} orthovanadates have been measured by using Mg K_{α} radiation. The O 1s, Re 4d, Fe 2p, and V 2p photoelectron spectra were studied. A very big difference was observed between ReFeO_{3} orthoferrites and ReVO_{4} orthovanadates, mainly the Fe 2p_{3/2} lines were double broader than V 2p_{3/2} ones,...
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