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Phase equilibria in the subsolidus region of the Na2MoO4-Hf(MoO4)2 system have been investigated. The existence of Na2Hf(MoO4)3 was confirmed, and a new binary molybdate, Na8Hf(MoO4)6, has been found, whose crystal structure with dimensions a = 20.661(3) Å, b = 9.816(1) Å, c = 13.796(3) Å, β = 113.47(1)°, Z = 4, space group C2/c, R = 0.023 is similar to that of K8Hf(MoO4)6. In the structure, each...
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