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The reactions of the pincer hydroxide complexes [(iPrPCP)M(OH)] (M=Ni, Pd) with dimethyl carbonate (DMC), and a set of organic electrophiles including benzaldehyde have been investigated in the context of our ongoing investigation on the synthesis of alkyl carbonates from CO2 and alcohols. The final outcome of such reactions is diverse, but for PhCHO and DMC the first step is a mechanistically similar...
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