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The kinetics of the complexation reactions of Ba2+ and Sr2+ in AN and 95:5 wt% AN:DMF were studied and the kinetic parameters for the decomplexation step, Ea, ΔH#, ΔS# and ΔG#, were determined in the temperature range of 17–47 °C. Kinetic parameters reveal that both dissociative and biomolecular mechanisms contribute to the exchange of the 30C10 complexes. Furthermore, the 30C10·Ba2+ complex was...
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