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Introducing phenylphosphonic acid (H2PPA) into the Ag/tBuSH assembly system has produced a family of nanoscale‐sized, high‐atom number, silver thiolate/PPA nests (SD/Ag45 a, SD/Ag66 a, and SD/Ag73 a) with impressive core–shell features. SD/Ag45 a is a 45‐atom ellipsoid comprised of an Ag36 shell trapping an Ag9S2 three‐bladed rotor inside. SD/Ag66 a comprises an inner rod‐like Ag20 core and an outer...
Compared with the well‐known anion‐templated effects in shaping silver thiolate clusters, the influence from the organic ligands in the outer shell is still poorly understood. Herein, three new benzoate‐functionalized high‐nuclearity silver(I) thiolate clusters are isolated and characterized for the first time in the presence of diverse anion templates such as S2−, α‐[Mo5O18]6−, and MoO42−. Single‐crystal...
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