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Multiple electrochemical pathways…︁ for a new class of supramolecular Ru/Rh bimetallic photocatalysts have been uncovered. The unusual redox chemistry of these species highlights the complexity of possible pathways operative in the photochemical reduction of H2O to H2 by these Ru/Rh systems. Halide loss competes with Rh reduction and in the presence of H2O additional species are possible for each...
Unusual and unprecedented multipathway electrochemical mechanisms for a new class of supramolecular Ru/Rh bimetallic photocatalysts have been uncovered. The near isoenergetic Rh(dσ*) and bridging ligand(π*) molecular orbitals and a rate of halide loss that occurs on the cyclic voltammetry timescale provide a series of closely related complexes which display four different electrochemical mechanisms...
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