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A rapid, atom‐efficient, cross‐coupling reaction of triarylbismuths with aryl bromides or aryl iodides was reported, and the reaction involves the use of a catalytic amount of polystyrene‐supported palladium in the presence of KF as base in DMSO at 105 °C in an open atmosphere. All three aryl groups of the triarylbismuths participated in the reaction and produced polyfunctional biaryls in excellent...
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