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Catalyst‐free addition of ketone enolate to non‐activated multiple C−C bonds involves non‐complementary reaction partners and typically requires super‐basic conditions. On the other hand, highly aggregated or solvated enolates are not reactive enough to undergo direct addition to alkenes or alkynes. Herein, we report a new anionic cascade reaction for one‐step assembly of intriguing molecular scaffolds...
Catalyst‐free addition of ketone enolate to non‐activated multiple C−C bonds involves non‐complementary reaction partners and typically requires super‐basic conditions. On the other hand, highly aggregated or solvated enolates are not reactive enough to undergo direct addition to alkenes or alkynes. Herein, we report a new anionic cascade reaction for one‐step assembly of intriguing molecular scaffolds...
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