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Saddle up! Saddle‐distorted SnIV porphyrin complexes form stable conglomerates with trinuclear Ru clusters with use of pyridine carboxylates as linkers (see figure). These novel dyads exhibit efficient photoinduced electron transfer, in which Sn porphyrin moieties act as electron donors and Ru clusters act as electron acceptors.
A series of conglomerates consisting of trinulcear RuIII clusters as electron acceptors and saddle‐distorted SnIV–dodecaphenylporphyrin complexes as electron donors was synthesized. Photoinduced electron transfer was observed in which both forward and backward transfer occurred in the Marcus inverted region, to afford electron‐transfer states of the conglomerates. For more details see the Full Paper...
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