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Extrem lichtempfindliches gelbes Arsen (As4) reagiert mit schwach koordinierten Silber‐Kationen zu lichtstabilem [Ag(η2‐As4)2] [Al{OC(CF3)3}4], dem ersten homoleptischen Arsenkomplex. Dichtefunktionalrechnungen und Raman‐Spektroskopie zeigen klar die Koordination zweier intakter As4‐Tetraeder in diesem Komplex. Der beispiellose Komplex wird als As4‐Übertragungsreagens verwendet, was durch die Synthese...
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