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(–)‐Berkelic acid is an architecturally unique secondary metabolite isolated from an extremophilic Penicillium species. In this paper, we describe a very simple protocol to construct the central core of this natural product. Using this strategy, not only (–)‐berkelic acid, but also a small library of analogues has been accessed. The key point of our protocol is a remarkable silver‐catalysed cascade...
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