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Three new biomimetic photocatalyts based on [2Fe2S]-Hases model compound, namely {(μ-pdte) [Fe(CO)3][Fe(CO)2L], μ-pdte = μ2-S(CH2)2CH[(CH2)3COOCH3]S-μ2, L = CO(1), L = PPh3(2)}, (μ-pdte) [Fe(CO)3] [Fe(CO) (phen)] (3), have been synthesized and characterized by elemental analysis, spectroscopy and particularly X-ray crystallography crystal structure analysis for 1. Visible-light-driven H2 evolution...
A new binuclear cobalt complex, namely [Co 2 (dmgH) 4 (μ-4,4′-bpy)Cl 2 ](1), had been synthesized by the reaction of [Co(dmgH)(dmgH 2 )Cl 2 ] with 4,4′-bipyridine(μ-4,4′-bpy) and characterized by IR, 1 H NMR, CV. An efficient homogeneous photocatalytic system was constructed by combination of noble-metal-free cobalt complex as catalyst, Eosin Y dye (EY...
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