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This paper presents an application of two recently developed methodologies to the synthesis of naturally occurring (–)‐aphanorphine. The first method involves an indium‐mediated stereoselective α‐aminoallylation of aldehydes to prepare enantioenriched homoallylic amine derivatives. The second is the epoxidation and regioselective opening of the epoxide to afford 2‐substituted 3‐pyrrolidinols. The...
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