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Coordination Chemistry The coordination of a geminal phosphorus–aluminum Lewis pair to organo‐gold complexes leads to unprecedented Au→Al interactions, which have been authenticated by X‐ray diffraction and analyzed by DFT calculations. For more details see the Communication by D. Bourissou et al. on page 74 ff.
Hitherto unknown Au→Al interactions have been evidenced upon coordination of the geminal phosphorus–aluminum Lewis pair Mes2PC(CHPh)AltBu2 (Mes=2,4,6‐trimethylphenyl). Four different gold(I) complexes featuring alkyl (Me), aryl (Ph, C6F5), and alkynyl (CCPh) co‐ligands have been prepared. X‐ray diffraction analyses show that P→Au→Al bridging coordination induces noticeable bending of the ligand...
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