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A new structural arrangement Te3(RPIII)3 and the first crystal structures of organophosphorus(III)–tellurium heterocycles are presented. The heterocycles can be stabilized and structurally characterized by the appropriate choice of substituents in Tem(PIIIR)n (m=1: n=2, R=OMes* (Mes*=supermesityl or 2,4,6‐tri‐tert‐butylphenyl); n=3, R=adamantyl (Ad); n=4, R=ferrocene (Fc); m=n=3: R=trityl (Trt), Mesor...
Phosphorus sulfides have been known for over 270 years and are familiar to us in strike‐anywhere matches, which contain P4S3. Many phosphorus–sulfur and phosphorus–selenium compounds have been discovered and characterized but, in contrast, phosphorus–tellurium compounds are quite rare, since it is difficult to stabilise the PTe and PTe bonds. In their Full paper on page 704 ff. J. D. Woollins and...
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