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The inside cover picture, provided by Ming Bao and co‐workers, illustrates the unprecedented remote allylation of chloromethyl(hetero)arenes with allyl pinacolborate. The palladium‐catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate proceeded smoothly via η3‐benzylpalladium intermediates to provide para‐allylated dearomatization products or para‐allylated...
The palladium‐catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para‐allylated dearomatization products or para‐allylated arenes in satisfactory to good yields. 2‐(Chloromethyl)thiophenes and 2‐(chloromethyl)furans bearing substituents on the 5‐positions...
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