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Discovered the Ruthenium(II) catalysed highly stereo‐ and regioselective protocol for the oxidative C‐3 alkenylation of indolizines and pyrrolo[1,2‐a]quinolines. The methodology represents the first example for the directing group assisted C–C bond formation reaction of the indolizines. Under mild reaction conditions, this method provides an ample substrate scope to produce C‐3 alkenyl indolizines...
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