The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Very recently, in situ cryospray-assisted variable temperature mass spectrometry (VT-MS) has been used to obtain the first convincing evidence for a HO–Fe V =O intermediate in the catalyst system [( Me2 PyTACN)Fe II (OTf) 2 ] (4)/H 2 O 2 ( Me2 PyTACN=1-(2′-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane, OTf=OSO 2 CF 3 )....
A computational study based on standard Density Functional Theory and polarized continuum model has been carried out for investigating the essential mechanistic features occurring in the catalytic oxidation of two model substrates, namely ethylene and 1,3-butadiene, promoted by vanadyl acetylacetonate [VO(acac) 2 ] in the presence of hydrogen peroxide. Results, showing in general a qualitative...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.