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Quasireversible adducts of dioxygen with Cu(I) complexes are of interest as models for dioxygen transport proteins, for oxygen-dependent copper redox enzymes, and for low-molecular oxidation and oxygenation catalysts. Depending on ligand denticity and structural factors dioxygen binds in various geometries and metal:O 2 ratios to the reduced copper centers. Kinetic investigations produce detailed...
In the last 20 years, the reaction of many different Cu I complexes and with dioxygen has been described. There is quite a big variety in their coordination geometry and most of them have been characterized by X-ray crystallography. Beyond structural information, stopped-flow kinetics experiments have provided additional mechanistic insights. In the particular systems [(BQPA)Cu I ]...
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