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We have developed two strategies to optimize Pd catalysts. On one hand, Ag was introduced into Pd and then they were applied to the selective hydrogenation of citral under mild conditions. The addition of metallic Ag could tune the selectivity of Pd and made it suitable for the selective hydrogenation of the conjugated double bond. The selectivity of citronellal increased from 0 (for Pd/C and Pd0.7...
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