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X-ray absorption and photoelectron spectroscopies are used to study the adsorption and reaction of Mn films deposited on TiO 2 (110) at 25°C and after annealing to ∼650°C. Fractional monolayer coverages of Mn at 25°C produce a reactive, disordered interface consisting of reduced Ti cations and oxidized Mn overlayer atoms. Metallic Mn is found only for thicker layers at 25°C. Annealing Mn films...
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