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Photoreactive molecular crystals have been intensively investigated as next‐generation functional materials. Changes in physicochemical properties are usually interpreted in terms of static pre‐ and post‐reaction molecular structures and packings determined by X‐ray structure analysis. However, to elucidate the dynamic properties, it is necessary to understand the dynamic nature of photochemical kinetics...
Some organic molecules undergo cooperative photoreaction processes in crystals, which have received little attention. An appropriate understanding of the basic reaction process is important for a dynamic understanding of property changes. In this Review article, K. Morimoto et al. summarize multiple examples of photochemical reactions in the crystalline phase that do not follow classical kinetic behavior...
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