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Clusterchemie. Im Forschungsartikel auf S. 1196 berichten Simone Sanna, Sangam Chatterjee, Doreen Mollenhauer, Stefanie Dehnen et al. über Untersuchungen der weitgehend unerforschten Siliciumchalkogenid‐Cluster [(RSi)4S6] und deren Reaktion mit [AuCl(PPh3)].
Zwei Arten intermetalloider Clusterarchitekturen werden aus Reaktionen von binären Zintl‐Anionen (Tt2Pn2)2− (Tt=Ge, Sn, Pb; Pn=As, Sb, Bi) mit [(PPh3)AuMe] erhalten, wie S. Dehnen et al. in ihrem Forschungsartikel auf S. 16781 beschreiben: Während Kombinationen schwererer Atome zur Rekonstruktion der binären Vorstufe unter Bildung von {[AuTt5Pn3]2}4− führen (nach links), ergibt das leichteste Homolog...
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