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Films of layered double hydroxides (M/Al-LDHs) with M=Ni, Zn have been fabricated on a porous anodic alumina/aluminum (PAO/Al) substrate via an in situ crystallization technique. The Ni/Al-LDH film has an orientation in which the ab-faces of the platelets are all perpendicular to the substrate whilst the LDH crystallites in the Zn/Al-LDH film are randomly orientated. Furthermore, the interlayer galleries...
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