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We report the spectroscopic characterization of cGMP, which has an important biological role as a second messenger. NMR and Raman spectroscopies were used to characterize the cGMPH and cGMPNa structure in solution (water and dimethylsulfoxide). The spectroscopic results show that for cGMPH in dimethylsulfoxide the N7 position is free and the proton is localized on the phosphate group. By addition...
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