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A new organic–inorganic hybrid material with the formula [C8H12N]3BiCl6 has been synthesized and characterized by spectroscopic techniques and single crystal X-ray structure determination. This compound crystallizes in the non-centrosymmetric space group Pna21 of the orthorhombic system with crystallographic parameters a=25.5620(2), b=16.7170(5), c=7.8840(4)Å, V=3369.0(2)Å3 and Z=4. Its structure...
The synthesis, crystal structure and spectroscopic characterization of a new chlorocadmate template by the 1-(2-hydroxyethyl)piperazine ligand are reported. In the atomic arrangement, the CdCl5O entities are deployed in corrugated rows along the a-axis at y = 1/4 and y = 3/4 to form layers parallel to the (a,b) plane. In these crystals, piperazinediium cations are in a chair conformation and are inserted...
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