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Reversible addition‐fragmentation chain transfer (RAFT) polymerization was performed in the presence of a new RAFT agent based on bisphenol A and modified clays and successfully prepared polystyrene/MMT nanocomposite. The structure of RAFT agent was investigated by Fourier transform infrared spectroscopy (FT‐IR) and proton nuclear magnetic resonance spectroscopy (1H NMR). The polymer had well‐defined...
Surface‐initiated reversible addition fragmentation chain transfer polymerisation of styrene was conducted from the surface of Laponite clay particles. A new cationic chain transfer agent, 2‐(2‐(butylthio‐carbonothioylthio)propanoyloxy)‐N,N,N‐trimethylethanaminium iodide was synthesised and attached to the clay surface from which polymerisation was initiated. A free RAFT agent, ethyl 2‐(butylthiocarbonothioylthio)propanoate...
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