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The front cover image illustrates the complex mixture of a selective copper‐mediated reaction of a bromobenzene bearing a bromoalkanoyl chain to an amine‐azide. It proceeds stepwise via a bis‐azide intermediate and produces copper nanostructures simultaneously, which grow on the PTFE stirring bar. The copper in the reaction mixture is responsible for the aryl azide reduction, and the mild protocol...
Aryl amines are synthesized from halobenzenes via copper mediated reactions employing sodium azide under mild conditions in ethanol/water. The reaction proceeds stepwise via the aryl azide, which is reduced to the corresponding amine in‐situ. The methodology allows syntheses of amines from corresponding para‐, meta‐ and ortho‐bromobenzenes bearing electron withdrawing groups. Bifunctional halobenzenes...
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