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We have performed an XPS, TDS, ISS and LEED investigation on the adsorption of ruthenium carbonyl, Ru 3 (CO) 12 on a Co(0001) surface. The adsorption of the carbonyl is molecular at 120 K and its dissociation occurs at 300 K via desorption of CO molecules. The desorption of CO is completed above 500 K, after which XPS and ISS indicate an atomically clean bimetallic surface, and...
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