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The potential of the heterogeneous catalyst 10 % Pd/C in the direct arylation of (poly)fluorobenzene derivatives with aryl bromides has been investigated. In general, high yields of biaryl derivatives were obtained by using tri‐, tetra‐, and pentafluorobenzenes, whereas mono‐ and difluorobenzenes exhibited poor reactivity. The regioselectivities of the arylation reactions were similar to those observed...
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